Plasma
In physics and chemistry, a plasma is an ionized gas, and is usually considered to be a distinct phase of matter. "Ionized" in this case means that at least one electron has been dissociated from a significant fraction of the molecules. The free electric charges make the plasma electrically conductive so that it couples strongly to electromagnetic fields. This fourth state of matter was first identified by Sir William Crookes in 1879 and dubbed "plasma" by Irving Langmuir in 1928, because it reminded him of a blood plasma
Characteristics
The term plasma is generally reserved for a system of charged particles large enough to behave as one. Even a partially ionized gas in which as little as 1% of the particles are ionized can have the characteristics of a plasma (i.e. respond to magnetic fields and be highly electrically conductive).
In technical terms, the typical characteristics of a plasma are:
Debye screening lengths that are short compared to the physical size of the plasma.
Large number of particles within a sphere with a radius of the Debye length.
Mean time between collisions usually is long when compared to the period of plasma oscillations.
Temperatures
The central electrode of a plasma lamp, showing a glowing blue plasma streaming upwards. The colors are a result of the radiative recombination of electrons and ions and the relaxation of electrons in excited states back to lower energy states. These processes emit light in a spectrum characteristic of the gas being excited.The defining characteristic of a plasma is ionization. Although ionization can be caused by UV radiation, energetic particles, or strong electric fields (processes that tend to result in a non-Maxwellian electron distribution function), it is more commonly caused by heating the electrons in such a way that they are close to thermal equilibrium so the electron temperature is relatively well-defined. Because the large mass of the ions relative to the electrons hinders energy transfer, it is possible for the ion temperature to be very different from (usually lower than) the electron temperature.
The degree of ionization is determined by the electron temperature relative to the ionization energy (and more weakly by the density) in accordance with the Saha equation. If only a small fraction of the gas molecules are ionized (for example 1%), then the plasma is said to be a cold plasma, even though the electron temperature is typically several thousand degrees. The ion temperature in a cold plasma is often near the ambient temperature. Because the plasmas utilized in plasma technology are typically cold, they are sometimes called technological plasmas. They are often created by using a very high electric field to accelerate electrons, which then ionize the atoms. The electric field is either capacitively or inductively coupled into the gas by means of a plasma source, e.g. microwaves. Common applications of cold plasmas include plasma-enhanced chemical vapor deposition, plasma ion doping, and reactive ion etching.
A hot plasma, on the other hand, is nearly fully ionized. This is what would commonly be known as the "fourth-state of matter". The Sun is an example of a hot plasma. The electrons and ions are more likely to have equal temperatures in a hot plasma, but there can still be significant differences.
Potentials
Lightning is an example of plasma present at Earth's surface. Typically, lightning discharges 30 thousand amps, at up to 100 million volts, and emits light, radio waves, x-rays and even gamma rays [1]. Plasma temperatures in lightning can approach 28,000 kelvins and electron densities may exceed 1024/m3.Since plasmas are very good conductors, electric potentials play an important role. The potential as it exists on average in the space between charged particles, independent of the question of how it can be measured, is called the plasma potential or the space potential. If an electrode is inserted into a plasma, its potential will generally lie considerably below the plasma potential due to the development of a Debye sheath. Due to the good electrical conductivity, the electric fields in plasmas tend to be very small, although where double layers are formed, the potential drop can be large enough to accelerate ions to relativistic velocities and produce synchrotron radiation such as x-rays and gamma rays. This results in the important concept of quasineutrality, which says that, on the one hand, it is a very good approximation to assume that the density of negative charges is equal to the density of positive charges (), but that, on the other hand, electric fields can be assumed to exist as needed for the physics at hand.
The magnitude of the potentials and electric fields must be determined by means other than simply finding the net charge density. A common example is to assume that the electrons satisfy the Boltzmann relation, . Differentiating this relation provides a means to calculate the electric field from the density: .
It is, of course, possible to produce a plasma that is not quasineutral. An electron beam, for example, has only negative charges. The density of a non-neutral plasma must generally be very low, or it must be very small, otherwise it will be dissipated by the repulsive electrostatic force.
In astrophysical plasmas, Debye screening prevents electric fields from directly affecting the plasma over large distances (ie. greater than the Debye length). But the existence of charged particles causes the plasma to generate and be affected by magnetic fields. This can and does cause extremely complex behavior, such as the generation of plasma double layers, an object that separates charge over a few tens of Debye lengths. The dynamics of plasmas interacting with external and self-generated magnetic fields are studied in the academic discipline of magnetohydrodynamics.
Complex plasma phenomena
Tycho's Supernova remnant, a huge ball of expanding plasma. Langmuir coined the name plasma because of its similarity to blood plasma, and Hannes Alfvén noted its cellular nature. Note also the filamentary blue outer shell of X-ray emitting high-speed electrons.Plasma may exhibit complex behaviour. And just as plasma properties scale over many orders of magnitude (see table above), so do these complex features. Many of these features were first studied in the laboratory, and in more recent years, have been applied to, and recognised throughout the universe. Some of these features include:
Filamentation, the striations or "stringy things" seen in a "plasma ball", the aurora, lightning, electric arcs, and nebulae. They are caused by larger current densities, and are also called magnetic ropes or plasma cables.
Double layers, localised charge separation regions that have a large potential difference across the layer, and a vanishing electric field on either side. Double layers are found between adjacent plasmas regions with different physical characteristics, and can accelerate ions and produce synchrotron radiation (such as x-rays and gamma rays).
Birkeland currents, a magnetic-field-aligned electric current, first observed in the Earth's aurora, and also found in plasma filaments.
Circuits. Birkeland currents imply electric circuits, that follow Kirchhoff's circuit laws. Circuits have a resistance and inductance, and the behaviour of the plasma depends on the entire circuit. Such circuits also store inductive energy, and should the circuit be disrupted, for example, by a plasma instability, the inductive energy will be released in the plasma.
Cellular structure. Plasma double layers may separate regions with different properties such as magnetization, density, and temperature, resulting in cell-like regions. Examples include the magnetosphere, heliosphere, and heliospheric current sheet.
Critical ionization velocity in which the relative velocity between an ionized plasma and a neutral gas, may cause further ionization of the gas, resulting in a greater influence of electomagnetic forces.
Ultracold plasmas
It is also possible to create ultracold plasmas, by using lasers to trap and cool neutral atoms to temperatures of 1 mK or lower. Another laser then ionizes the atoms by giving each of the outermost electrons just enough energy to escape the electrical attraction of its parent ion.
The key point about ultracold plasmas is that by manipulating the atoms with lasers, the kinetic energy of the liberated electrons can be controlled. Using standard pulsed lasers, the electron energy can be made to correspond to a temperature of as low as 0.1 K a limit set by the frequency bandwidth of the laser pulse. The ions, however, retain the millikelvin temperatures of the neutral atoms. This type of non-equilibrium ultracold plasma evolves rapidly, and many fundamental questions about its behaviour remain unanswered. Experiments conducted so far have revealed surprising dynamics and recombination behaviour that are pushing the limits of our knowledge of plasma physics.
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